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Unexpected Hosts

Spider-Man (Symbiote), Mister Fantastic, Mysterio, Deadpool

Synergy Champions: For each unique Buff on the Synergy Champion and each unique Debuff on the Opponent, gain +295 Critical Rating. Max: 3 Buffs and 3 Debuffs.
Unique Synergy: Does not stack with duplicate synergies.

Wardrobe Malfunction

Spider-Man (Symbiote), Spider-Man (Classic)

Unique Synergy: Does not stack with duplicate synergies.

Heavy Lies the Mantle

Black Tarantula, Falcon (Joaquin Torres), Kushala

Unique Synergy: Does not stack with duplicate synergies.

Puño Cerrado

Black Tarantula, Daredevil (Classic), Absorbing Man

Unique Synergy: Does not stack with duplicate synergies.

White and Black and Black and White

Black Tarantula, White Tiger, Mister Negative

Unique Synergy: Does not stack with duplicate synergies.

Working Overtime

Hobgoblin (Phil Urich), Kingpin

Unique Synergy: Does not stack with duplicate synergies.

Laughter Amongst The Stars

Hobgoblin (Phil Urich), Red Goblin

Unique Synergy: Does not stack with duplicate synergies.

My Own Twist

Hobgoblin (Phil Urich), Green Goblin

Unique Synergy: Does not stack with duplicate synergies.

Hell on Earth

Shatterstar, Mephisto

Unique Synergy: Does not stack with duplicate synergies.

Son of Gaveedra

Shatterstar, Longshot

Synergy Champions: Gain +5% Attack Rating.
Unique Synergy: Does not stack with duplicate synergies.

Parents of Gaveedra

Shatterstar, Longshot, Dazzler

Unique Synergy: Does not stack with duplicate synergies.

Sky-High Ratings

Shatterstar, Spiral, Mojo

Unique Synergy: Does not stack with duplicate synergies.

Threats to the Cosmos

Phyla-Vell, Annihilus, Ultron (Classic), Thanos, Adam Warlock, Ronan

Other Synergy Champions: +8% Attack Rating when fighting #Heroes.
Unique Synergy: Does not stack with duplicate synergies.

Better Luck Next Time

Phyla-Vell, Nova, Star-Lord

Unique Synergy: Does not stack with duplicate synergies.

Life and Death

Phyla-Vell, Adam Warlock

Unique Synergy: Does not stack with duplicate synergies.

A Cost too Great

Moondragon, Phyla-Vell

Unique Synergy: Does not stack with duplicate synergies.

No Matter the Cost

Phyla-Vell, Moondragon

Unique Synergy: Does not stack with duplicate synergies.

Medley Relay

Wave, Toad, QuickSilver, Pixie

Synergy Champions: Backing up to the left wall begins a 30 second timer. If the Opponent hits the right wall within that time, gain a +50% Fury Passive for 20 seconds. The timer cannot restart until it has failed or the Fury has ended.
Unique Synergy: Does not stack with duplicate synergies.

Untouchable Heavy

Wave, Kitty Pryde, Morbius, Tigra

Synergy Champions: Charging Heavy outside of Specials grants an Untouchable Passive for 1 second, paused while charging or until an attack Misses. If it causes a Miss, it goes on cooldown for 30 seconds.
Unique Synergy: Does not stack with duplicate synergies.

Splash Attack

Wave, Namor, Attuma

Synergy Champions: Every hit includes a splash attack, which does nothing. Every 20 hits in the Combo Meter causes the next 2-3 hits to thrash, dealing an additional 120% of Attack Rating as a burst of Physical Damage.
Unique Synergy: Does not stack with duplicate synergies.